复合材料薄壁旋转梁的研究进展

本文综述了近年来复合材料薄壁旋转梁的研究进展,着重介绍了围绕梁平面外翘曲问题,各国学者在非线性梁理论、用解析法和有限元法构造复合材料薄壁梁模型方面做的工作,讨论了此领域需进一步研究的问题．      

高速逆流色谱法分离茶叶中的生物碱

以氯仿－甲醇－磷酸二氢钠缓冲液（２３ｍｍｏｌ／Ｌ,ｐＨ５．６）（体积比４∶３∶２）为溶剂系统,上相为固定相,下相为移动相,从茶叶的总生物碱中分离出三个成分,其中一个是咖啡碱,一个是茶碱,另一个待定。将分离结果与ＴＬＣ分离结果相比较,证实了高速逆流色谱法的有效及实用性。     

An unconditionally stable semi‐Lagrangian method for the spherical atmospherical shallow water equations

A semi‐implicit, semi‐Lagrangian, mixed finite difference–finite volume model for the shallow water equations on a rotating sphere is introduced and discussed. Its main features are the vectorial treatment of the momentum equation and the finite volume approach for the continuity equation. Pressure and Coriolis terms in the momentum equation and velocity in the continuity equation are treated semi‐implicitly. Moreover, a splitting technique is introduced to preserve symmetry of the numerical scheme. An alternative asymmetric scheme (without splitting) is also introduced and the efficiency of both is discussed. The model is shown to be conservative in geopotential height and unconditionally stable for 0.5≤θ≤1. Numerical experiments on two standard test problems confirm the performance of the model. Copyright © 2000 John Wiley & Sons, Ltd.     

横观各向同性轴对称磁电弹性旋转圆盘的三维解析解

从横观各向同性轴对称磁电弹性力学的控制方程出发直接求得旋转圆盘相应于离心力的特解,再利用位移、电势和磁势的通解推导出应力、电位移和磁感应强度的通解,在特解上叠加一个准调和函数形式的通解并满足边界条件的方法,得到了横观各向同性轴对称磁电弹性旋转圆盘的三维解析解．     

Microstructural investigation of high‐speed melt‐spun nylon 6 fibers produced with variable spinning speeds

The structural details of high‐speed melt‐spun nylon 6 fibers at spinning speeds ranging from 4500 to 6100 m/min were investigated by solid‐state proton nuclear magnetic resonance (¹H NMR) spectroscopy, density and birefringence measurements, differential scanning calorimetry (DSC), and X‐ray diffraction (XRD). The analyses of the proton spin‐lattice relaxation times in the rotating frame and correlation times confirmed the existence of three different phases, the immobile crystalline, intermediate rigid amorphous, and mobile amorphous regions, in the fiber sample. At spinning speeds lower than 5200 m/min, the portion of the crystalline phase increased at the expense of the rigid amorphous region and then reached a plateau afterward, from which the mobile amorphous portion increased. Combined analyses of density and birefringence measurements, DSC, and XRD in conjunction with NMR results indicated that the formation of the γ crystal became predominant compared to that of the α crystal. The orientation factor of the crystalline phase increased slightly with increasing spinning speed, whereas the amorphous orientation factor decreased because of the increase of the purely amorphous region. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 1285–1293, 2000     

Spectral methods for the simulation of incompressible flows in spherical shells

A spatial discretization of the incompressible Navier–Stokes equation is presented in which the velocity is decomposed using poloidal and toroidal scalars whose spatial dependence is given in terms of spherical harmonics and Chebychev polynomials. The radial resolution needs to be large enough at any given angular resolution in order to avoid instability in the simulation of rotating flows. Several semi‐implicit time steps are discussed. The most accurate scheme is an integrating factor technique. Copyright © 1999 John Wiley & Sons, Ltd.     

Dynamic mechanical and solid-state NMR determination of molecular-scale heterogeneity in a raw elastomer,a microcrystalline polymer,and their blend

Dynamic mechanical and solid-state ¹³C nuclear magnetic resonance (NMR) analyses have been used to assess a molecular-scale heterogeneity in a raw elastomer (butadiene-acrylonitrile copolymer elastomer, NBR), a microcrystalline polymer (poly(vinyl chloride), PVC), and their 50/50 blend. The presence of the microcrystalline heterogeneity in PVC and in the blend was characterized by the temperature dependence of the frequency-swept dynamic mechanical behavior. The NMR T_1ρ relaxation experiments with cross-polarization (CP) and magic-angle spinning (MAS) revealed that (1) NBR contained a substantial fraction (ca. 27%) of a molecular-scale heterogeneity identified as butadiene blocks, (2) the fraction of microcrystallites in PVC was ca. 14%, (3) pure phases of both component polymers were present in the blend, dispersed in the mixed matrix, (4) the upper limit of the heterogeneous domains was estimated to be ca. 2.4 nm, and (5) fractions of heterogeneity tend to increase upon blending, indicating that the solubility of the butadiene block and syndiotactic PVC block decreases in the blend. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys, 35: 709–716, 1997     

Simulation of particle settling in rotating and non-rotating flows of non-Newtonian fluids

Finite element solutions are presented for the flow of Newtonian and non-Newtonian fluids around a sphere falling along the centreline of a cylindrical tube. Both rotating and stationary tube scenarios are considered. Calculations are reported for three different inelastic constitutive models that manifest shear-thinning, extension-thickening and their combination. The influence of inertia and these various forms of viscous response are examined for their influence upon the drag on the settling particle and the structure of the flow. Simulations are performed by employing a semi-implicit time marching Taylor–Galerkin/pressure-correction finite element algorithm, a fractional-staged scheme of second-order-accuracy. © 1998 John Wiley & Sons, Ltd.     

高速干铣削钛合金时涂层硬质合金刀具磨损机理研究

采用CVD涂层硬质合金可转位立铣刀对钛合金(Ti-6Al-4V)进行了高速干铣削试验,采用扫描电子显微镜(SEM)观察刀具的磨损形貌,通过能谱分析(EDS)分析失效刀具表面的元素分布,并对刀具的主要磨损机理进行了分析.研究结果表明:使用涂层硬质合金刀具高速干铣削Ti-6Al-4V时,刀具的失效机理主要为磨粒磨损、粘结磨损、氧化磨损、扩散磨损和热-机械疲劳磨损的综合作用.刀具刚参与切削时,刀具后刀面会产生粘结和由于摩擦引起的擦伤,粘结层在断续冲击作用下的脱落过程还会造成后刀面涂层的剥落;随着刀具进一步的磨损,涂层剥落、粘结磨损及磨粒磨损伴随整个刀具失效过程,且还会出现氧化磨损、扩散磨损和疲劳裂纹等.切削速度越高,新产生的钛合金切屑就越容易燃烧,使刀具粘结、氧化和扩散以及热-机械疲劳等磨损加剧.